Alumina-supported oxime for the degradation of sarin and diethylchlorophosphate

1-(4-Chlorophenyl))-N-hydroxymethanimine and cyclohexyl-N-hydroxymethanimine were synthesized and a well-established oxime, i.e., 2-[(hydroxyimino)methyl]-1-methylpyridinium chloride was purchased. Thereafter; all were loaded over Al₂O₃ using incipient wetness technique. The prepared systems were characterized using surface area analyzer, scanning electron microscope, energy dispersive X-ray spectrophotometer, Fourier transform infrared spectrophotometer and thermogravimetric analyzer. Kinetics of the degradation of sarin (GB) and simulant, i.e. diethylchlorophosphate (DEClP) was studied over synthesized oxime impregnated Al₂O₃ and results were compared with well reported oxime impregnated Al₂O₃. Kinetics of reaction was found to be following the pseudo first order reaction kinetics. The order of reactivity of the prepared systems was found to be cyclohexyl-N-hydroxymethanimine/Al₂O₃ > 1-(4-chlorophenyl)-N-hydroxymethanimine/Al₂O₃ > 2-[(hydroxyimino)methyl]-1-methylpyridinium chloride/Al₂O₃ > Al₂O₃. From the reaction kinetics it was observed that the reaction with DEClP was faster than with GB. Cyclohexyl-N-hydroxymethanimine/Al₂O₃ was found to be the most reactive system with half-life of 0.94 and 15 h for DEClP and GB respectively.     

Metallic components of traffic-induced urban aerosol, their spatial variation, and source apportionment

This study proposes a practical method to estimate elemental composition and distribution in order to attribute source and quantify impacts of aerosol particles at an urban region in Kolkata, India. Twelve-hour total particulates were collected in winter (2005–2006) and analyzed by energy-dispersive X-ray fluorescence technique to determine multi-elemental composition, especially trace metals. The aerosols consist of various elements including K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Se, and Pb which exhibit significant concentration at various sites (p?<?0.05). The concentration of different metallic elements were found in the order of Zn ?> ?Pb ?> ?Ni ?> ?Cu ?> ?Cr ?>? Co. Statistical multivariate analysis and correlation matrix analyses were performed for factor identification and consequent source apportionment. Contour profiles demonstrate spatial variation of elemental compositions indicating possible source contribution along with meteorological influences. Spatial differences were clearly most significant for Zn, Ni, Pb, and Cu reflecting the importance of anthropogenic inputs, primarily from automobile sources.     

Microbial degradation of pyridine using Pseudomonas sp. and isolation of plasmid responsible for degradation

Pseudomonas (PI2) capable of degrading pyridine was isolated from the mixed population of the activated sludge unit which was being used for treating complex effluents, the strain was characterized. Aerobic degradation of pyridine was studied with the isolated strain and the growth parameters were evaluated. Pyridine degradation was further conformed by chromatography (HPLC) analysis. The process parameters like biomass growth and dissolved oxygen consumption were monitored during pyridine degradation. In order to conform with the plasmid capability to degrade pyridine, the requisite plasmid was isolated and transferred to DH 5alpha Escherichia coli. The subsequent biodegradation studies revealed the ability of the transformed plasmid capability to degrade the pyridine.     

Evaluation of a fluorometric method for measuring low concentrations of ammonia in ambient air

A fluorometric method developed for measuring low concentrations of ammonium in marine and freshwater ecosystems was adapted for the analysis of ammonia in ambient air. The modified method entails collection of samples on an acid-treated solid adsorbent followed by analysis using a fluorometer. Optimal results were obtained using a commercially available sorbent tube containing 100 mg of acid-treated silica gel for sample collection, and an analytical protocol consisting of sample desorption in DI water, addition of orthopthaldialdehyde (OPA) working reagent, and room temperature incubation. Method accuracy and precision were evaluated by comparing experimentally determined quantities of ammonia to expected levels for sample loadings ranging from 0.16 [micro sign]g to 550 [micro sign]g-accuracy was generally within +/-20%. The estimated LOQ for the method is 0.08 [micro sign]g ammonia per sample which represents a 25-375-fold improvement in sensitivity compared to current NIOSH and OSHA methods for the measurement of ammonia in ambient air. The new method should be useful for applications requiring measurement of low concentrations of ammonia using personal sampling equipment or in the characterization of short-term fluctuations of ammonia concentrations in air.     

A comparative assessment of the impact of different occupations on workers' static musculoskeletal fitness.

An ergonomic assessment of the involvement of static muscular forces like back strength, grip strength and pinch strength in different occupations was made. A study was conducted on 45 normal adult males (15 subjects per group) which included video display terminal (VDT) operators, industrial workers and safety inspectors. Their maximum back strength, handgrip strength and pinch strength were measured with dynamometers. The observed values of back strength were significantly lower in VDT operators while significantly higher in safety inspectors and moderate in industrial workers. The values of grip strength and pinch strength of all sample groups were more or less similar. The findings clearly indicate that static muscular strength varies significantly in different occupations. Heavy static muscular load might lead to an accumulation of metabolic waste and toxins on the back resulting in lower back strength in VDT operators and industrial workers.     

The medicinal and aromatic plants business of Uttarakhand: A mini review of challenges and directions for future research

The medicinal and aromatic plants resources of Uttarakhand, India offer significant opportunities of employment and livelihood for rural communities and contribute a large share in the medicinal and aromatic plants trade of India. With the growing trade of medicinal and aromatic plants resources in the global market, the medicinal and aromatic plants business of Uttarakhand is also continuously growing in terms of trade volume, value and market reach. But, considering the ecological importance as well as unregulated exploitations of these resources, the growing business activities in this sector appear incompatible to the sustainability agenda. Through a mini review, this study assesses the medicinal and aromatic plants sector of Uttarakhand and identifies key challenges that seem incompatible for resource and business sustainability and offers some prospective research directions essential for identifying pragmatic solutions to support sustainability in the sector. This review identifies nine key challenges to sustainability in Uttarakhandʼs medicinal and aromatic plants sector. It is therefore pertinent that future research focus on the prevailing challenges of the medicinal and aromatic plants sector of Uttarakhand to develop strategies for sustainable business prospects.     

Allelopathic response of <Emphasis Type="Italic">Vetiveria zizanioides</Emphasis> (L.) Nash on members of the family Enterobacteriaceae and <Emphasis Type="Italic">Pseudomonas</Emphasis> spp.

The biological removal of phosphates was carried as a part of treatment strategy. Vetiveria zizanioides (L.) Nash belonging to the family Poaceae was used for biological removal of biostimulants. Vetiver reportedly has mycorrhizal association; besides having potential for removal of PO₄ ⁻³ also showed allelopathic affect on the microorganisms present in the water. In fact after a period of 96 h old roots of this plant have been found to have killing effects on the E. coli, Enterobacter spp. Pseudomonas spp. belonging to the family Enterobacteriaceae. The paper is opening a new face of study.     

A study of the workload of underground trammers in the Ranigang coal field area of West Bengal, India.

Thirty healthy trammers were examined in underground haulage mines during their normal activity. Physiological strain in terms of heart rate (HR) varied between 101.6 and 104.7 beats/min with mean net cardiac cost of 33.06 and 34.06 beats/min for younger and older groups respectively. The average relative cardiac cost was lower for younger subjects than for older ones. Oxygen consumption (VO2) was measured with an Oxylog-II machine (UK); subsequently values were estimated. Maximum aerobic capacity was estimated with an indirect method following a standard step test protocol. The responses revealed that the average VO2 during the activity was 0.75 and 0.8 L/min, which corresponded to energy expenditure (EE) of 3.8 and 3.97 Kcal/min for younger and older subjects respectively. The workload in terms of HR and EE was moderate, whereas the aerobic strain experienced by aged workers was above the acceptable level.     

Emissions from burning biofuels in metal cookstoves

Promoting stoves that burn wood and other biofuels more efficiently is one of the means to reduce fuel consumption, but such efficient stoves may also emit more carbon monoxide and total suspended particulates. In an earlier study, a standard chamber method was proposed to estimate emission factors from burning fuelwood (Acacia nilotica). Here that methodology is extended to measure emission factors from burning of dungcakes and crop residues (Brassica or mustard stalks)—common fuels in many developing countries. The amounts of carbon monoxide (CO) and total suspended particulates (TSP) emitted by four different models of stoves, when using each of the three biofuels, are measured.The CO emission factors range from 13–68 (g/kg) for fuelwood to 26–67 g/kg for dungcakes and 20–114 g/kg for crop residues, for particulates they range from 1.1–3.8 to 4.1–7.8 and 2.1–12.0 g/kg for the three fuels, respectively. On a per unit heat delivered basis, the emissions of CO and TSP from both dungcakes and crop residues are two to three times higher compared to those from fuelwood. While for some improved stove-fuel combinations, the increase in emission factors was offset by the increase in thermal efficiency, this was not always so and causes a dilemma. The more efficient stoves are found to have higher emission factors of both CO and TSP for all three fuels. Emissions per standard task (i.e, on a unit heat delivered basis) is proposed as a criterion to evaluate cookstoves.